Twenty-three-times Cup winners Athletic Bilbao were dumped out in sensational circumstances by tiny island side SD Formentera, who sneaked a 1-0 win at San Mames with a header by Alvaro Muniz deep in stoppage-time to reach the last 16 for the first time with a 2-1 aggregate victory.
Champions Barcelona came through a gruelling La Liga test at a rainswept San Mames on Sunday, beating Athletic Bilbao 1-0 thanks to Ivan Rakitic's first-half header.
Man Utd sign Mount from Chelsea on five-year deal
Italian champions Juventus have informed Athletic Bilbao that they will start talks with the La Liga club's Spain striker Fernando Llorente with a view to signing him, Bilbao said on Thursday.
Barcelona coach Luis Enrique is expecting another gruelling game at Athletic Bilbao when the La Liga champions visit San Mames on Sunday.
News of all that's transpired on and off the football field
Real Madrid coach Carlo Ancelotti is looking for a big improvement from his side when they play their first home game of the LaLiga season, against Valladolid on Sunday, with Kylian Mbappe making his Santiago Bernabeu debut
IMAGES from the Europa League matches played on Thursday
Inaki and Nico Williams encounter contrasting fortunes at the World Cup.
IMAGES from the Europa League matches played on Thursday
Here are five talking points from the weekend in La Liga:
The value of an in-form striker was underlined as Tottenham Hotspur, Liverpool and Athletic Bilbao needed goals from pivotal front men to grab vital wins that booked places in the Europa League last 32 on Thursday.
The Portugal forward will miss Real's league games against Villarreal, Getafe and Elche but will be available for the King's Cup semi-final, first leg at home to holders Atletico Madrid later on Wednesday and the return game next week.
The win leaves United in 15th place in the Europa League standings on six points from four games.
Stakeholders are confident the Spanish league season can resume in mid-June in closed stadiums without spectators, with fans not expected to be able to return to grounds until 2021.
The Copa del Rey semi-final draw will be made on Friday.
Manchester United and Liverpool, English football's two most decorated clubs, were drawn together in the last 16 of the Europa League on Friday.
Hazard extra-time goal sends 10-man Real Madrid through to Copa del Rey final.
Xavi mentioned again on Saturday that the club faced problems. Similar comments had reportedly annoyed Laporta earlier in the season.
IMAGES from Premier League matches played on Sunday.
Rodrygo and new recruit Jude Bellingham scored first-half goals to give Real Madrid a 2-0 win at Athletic Bilbao to kick off their LaLiga season.
Atletico Madrid moved a step closer to an unlikely Spanish title triumph when they battled back from a goal down to secure a 2-1 win at fourth-placed Athletic Bilbao in La Liga on Saturday.
The Manchester clubs' wretched continental seasons ended on Thursday as outclassed United and battling City suffered contrasting Europa League last-16 exits to an exhilarating Athletic Bilbao and a fortunate Sporting respectively.
Two goals from Lionel Messi and a poacher's strike from Bojan Krkic gave Barcelona a 3-0 win over Athletic Bilbao in their Spanish Super Cup second leg on Sunday for a 5-1 aggregate victory.
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Atletico Madrid's La Liga title challenge took a nosedive when they slumped to a shock 3-0 defeat at Osasuna on Sunday, leaving Real Madrid three points clear at the top.
Barcelona suffered their first league defeat of the season when they went down 1-0 at Athletic Bilbao while Arsenal stayed clear at the head of the Premier League.
Athletic Bilbao's Spanish Super Cup victory against Barcelona not only earned them their first major trophy in 31 years but also ended coach Ernesto Valverde's long wait for silverware.
Levante continued to defy their humble status as Valencia's second club when they beat Real Betis 3-1 to reclaim fourth place in La Liga on Monday.
Spain coach Vicente del Bosque sprung three surprises in his 23-man squad for the World Cup in South Africa, including Barcelona pair Victor Valdes and Pedro plus Athletic Bilbao midfielder Javi Martinez. Goalkeeper Valdes replaces Villarreal's Diego Lopez as Spain's third-choice behind number one and captain Iker Casillas of Real Madrid and number two Pepe Reina of Liverpool.
Barcelona must wait a bit longer before they can claim their La Liga crown after drawing 2-2 with Athletic Bilbao, while Paris St Germain and Juventus continued to close in on the French and Italian titles.
Barcelona's Sergi Roberto and Robert Lewandowski struck just before halftime to give the league leaders a 2-0 home win over lowly Cadiz on Sunday in their pursuit of a 27th Spanish title.
Athletic Bilbao and Atletico Madrid overcame German opposition to reach the Europa League semi-finals on Thursday while fellow Spaniards Valencia joined them by demolishing AZ Alkmaar.
Premier League-based trio Diego Costa, Juan Mata and Santi Cazorla were among a high-profile list of absentees when Spain coach Vicente Del Bosque named his provisional 25-man squad for Euro 2016 on Tuesday. Costa injured his hamstring against Liverpool in Chelsea's penultimate game of the season. Atletico Madrid striker Fernando Torres was also absent from the squad despite his improved form towards the end of the season, as were Arsenal midfielder Cazorla and Valencia forward Paco Alcacer, Spain's top scorer in their qualifying campaign.
Athletic Bilbao, conquerors of Manchester United in the previous round, continued their Europa League run by scoring three times in the last 20 minutes to win their quarter-final first leg tie 4-2 at Schalke 04 on Thursday.
IMAGES from the soccer matches played across leagues on Friday
Liverpool frustrated by 10-man Arsenal in League Cup semi stalemate
Atletico Madrid and Athletic Bilbao should serve up a Europa League final to remember on Wednesday and remind the continent that Spain is not just about Real Madrid or Barcelona.
The King's Cup final between record winners Barcelona and Athletic Bilbao on May 30 will be held at Barca's Nou Camp.
'Yesterday, he trained normally, and today he's taken this decision. We have accepted it. I spoke to him this morning, and he said he was leaving, and I understood.'
